Our estimation results confirm the role of biodiversity as a nature-based policy solution for climate change mitigation, shedding light on the policy actions that generate co-benefits by enhancing ecosystems’ capacity to mitigate climate change impacts, while conserving biodiversity and sustaining the flows of EGS for human livelihoods. Especially, nature-based mitigation policies are more cost-effective and better at coping with the ethic and inequality issues associated with distributional impacts of the policy actions, compared to the pure technical solutions to improving energy efficiency and reducing emissions. However, the strength of biodiversity as a nature-based policy option for climate change mitigation depends on both the nature of the EGS and the geographical area under consideration. Our estimation results confirm the role of biodiversity as a nature-based policy solution for climate change mitigation, shedding light on the policy actions that generate co-benefits by enhancing ecosystems’ capacity to mitigate climate change impacts, while conserving biodiversity and sustaining the flows of EGS for human livelihoods. Especially, nature-based mitigation policies are more cost-effective and better at coping with the ethic and inequality issues associated with distributional impacts of the policy actions, compared to the pure technical solutions to improving energy efficiency and reducing emissions. However, the strength of biodiversity as a nature-based policy option for climate change mitigation depends on both the nature of the EGS and the geographical area under consideration.